PRIORITY PROGRAM “Material Synthesis near Room Temperature”
Coordinator & Contact
Summary
Projects of the 2nd Funding Period
Projects of the 1st Funding Period
Mercator Fellow, 2nd Funding Period
Mercator Fellow, 1st Funding Period
Job Vacancies
PUBLICATIONS & AWARDS
Overall List, 2nd Funding Period
Overall List, 1st Funding Period
Media Reports
EVENTS
Lectures
Kick-off Meeting
Workshop on Synthesis Strategies in Ionic Liquids
Scientific Writing
Mid-Term Report Colloquium
Patent Law
In situ Methods
2nd International Conference
Career Development/Posdoctoral Proposals
Archive
MEASURES FOR EQUAL OPPORTUNITIES
General Information
Be WISE and Succeed
Mentoring for schoolgirls in
the STEM disciplines
Chemistry Camp 2018
Girls' Day 2018
Girls' Day 2019
Archive
LINKS
Chair of Inorganic Chemistry II
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An overall list of publications during the 2nd funding period
Molecular design and X-ray spectroscopy of & on iron nanocluster catalysts
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Stereoselective Alkyne Hydrogenation by using a Simple Iron Catalyst
B. J. Gregori, F. Schwarzhuber, S. Pöllath, J. Zweck, L. Fritsch, R. Schoch, M. Bauer, A. Jacobi von Wangelin,
ChemSusChem, 2019, 12, 3864-3870. |
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Bimetallic Co/Al nanoparticles in an ionic liquid: synthesis and application in alkyne hydrogenation
L. Schmolke, B. J. Gregori, B. Giesen, A. Schmitz, J. Barthel, L. Staiger, R. A. Fischer, A. Jacobi von Wangelin, C. Janiak,
New J. Chem., 2019, 43, 16583-16594. |
Base Metal Nanostructures via Ionic-Liquid-based Synthesis (BaseMet-IL)
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Bimetallic Nickel-Iridium and Nickel-Osmium Alloy Nanoparticles and Their Catalytic Performance in Hydrogenation Reactions
A. Egeberg, C. Dietrich, C. Kind, R. Popescu, D. Gerthsen, S. Behrens, C. Feldmann,
ChemCatChem, 2017, 9, 3534–3543. |
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Electrochemical Synthesis of III-V (GaN, InN, GaSb, InSb, AlSb) and Metal Sulfide (ZnS, GaS) Compound Semiconductors and their Nanostructures from Ionic Liquids
Low-Temperature Conversions of Complex Solid Precursors in Ionic Liquids: New Compounds and Insights into Reaction Principles
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Spontaneous Substitutions on Phosphorus Trihalides in Imidazolium Halide Ionic Liquids: A Grotthuss Diffusion of Anions?
O. Holloczki, A. Wolff, J. Pallmann, R. Whiteside, J. Hartley, M. A. Grasser, P. Nockemann, E. Brunner, Th. Doert, M. Ruck,
Chem. Eur. J., 2018, 16323-16331. |
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Low-temperature tailoring of copper-deficient Cu3-xP – electric properties, phase transitions and performance in Li ion batteries
A. Wolff, T. Doert, J. Hunger, M. Kaiser, J. Pallmann, R. Reinhold, S. Yogendra, L. Giebeler, J. Sichelschmidt, W. Schnelle, R. Whiteside, H.Q. N. Gunaratne, P. Nockemann, J. Weigand, E. Brunner, M. Ruck,
Chem.Mater., 2018, 7111–7123. |
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Mechanistic exploration of the copper(I) phosphide synthesis in phosphonium-based and phosphorus-free ionic liquids
M. Lê Anh, A. Wolff, M. Kaiser, S. Yogendra, J. Weigand, J. Pallmann, E. Brunner, M. Ruck, T. Doert,
Dalton Trans., 2017, 46, 15004–15011.
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On the Anion Exchange of PX3 (X = Cl, Br, I) in Ionic Liquids comprising Halide Anions
A. Wolff, J. Pallmann, E. Brunner, T. Doert, M. Ruck,
Z. Anorg. Allg. Chem., 2017, 643, 20–24.
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Preparation of intermetallic phases in ionic liquids
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Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids
L. Schmolke, S. Lerch, M. Bühlow, M. Siebels, A. Schmitz, J. Thomas, G. Dehm, C. Held, Th. Strassner, C. Janiak,
Dalton Trans., 2019, 11, 4073.
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Low-Temperature Approach to Solvent-Free Chalcogenidometalate Materials
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Synthesis and Structures of Compounds with Molecular, One-Dimensional or Two-Dimensional Selenido Cadmate Anions
I. Nußbruch, S. Dehnen,
Z. Anorg. Allg. Chem., 2018, in the print.
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K2Hg2Te3 – Straightforward and Large-Scale Mercury-Flux Synthesis of a Small-Band-Gap Photoconducting Material
G. Thiele, P. Bron, S. Lippert, F. Nietschke, O. Oeckler, M. Koch, B. Roling, S. Dehnen,
Inorg. Chem., 2018, in the print.
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[Hg4Te8(Te2)4]8–: A Heavy Metal Porphyrinoid Embedded in a Lamellar Structure
C. Donsbach, K. Reiter, D. Sundholm, F. Weigend, S. Dehnen,
Angew. Chem. , 2018, 129, 8906–8910.
Angew. Chem. Int. Ed., 2018, 57, 8770–8774. |
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Synthesis of intermetallic transition metal-main group metal nanoparticles in ionic liquids
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Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids
L. Schmolke, S. Lerch, M. Bühlow, M. Siebels, A. Schmitz, J. Thomas, G. Dehm, C. Held, Th. Strassner, C. Janiak,
Dalton Trans., 2019, 11, 4073.
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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand
M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel, C. Janiak,
Dalton Trans., 2018, 47, 8892.
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Synthesis of Rare Earth Metal and Rare Earth Metal Fluoride Nanoparticles in Ionic Liquids and Propylene Carbonate
M. Siebels, L. Mai, L. Schmolke, K. Schütte, J. Barthel, J. Yue, J. Thomas, B. Smarsly, A. Devi, R. A. Fischer, C. Janiak,
Beilstein J. Nanotechnol., 2018, 9, 1881–1894.
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Thermodynamic properties of selenoether-functionalized ionic liquids and their use for the synthesis of zinc selenide nanoparticles
K. Klauke, D. H. Zaitsau, M. Bülow, L. He, M. Klopotowski, T.-O. Knedel, J. Barthel, C. Held, S. P. Verevkin, C. Janiak,
Dalton Trans., 2018, 47 (14), 5083-5097.
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Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety
K. Klauke, I. Gruber, T.-O. Knedel, L. Schmolke, J. Barthel, H. Breitzke, G. Buntkowsky, C. Janiak,
Organometallics, 2018, 37 (3), 298-308.
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Synthesis of metal-fluoride nanoparticles supported on thermally reduced graphite oxide
A. Schmitz, K. Schütte, V. Ilievski, J. Barthel, L. Burk, R. Mülhaupt, J. Yue, B. Smarsly, C. Janiak,
Beilstein J. Nanotechnol., 2017, 8, 2474-2483.
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Multifunctional Soft Materials from and with Borate Ionic Liquids and Lanthanides
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Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-viscosity Ionic Liquids
J. Landmann, J. A. P. Sprenger, P. T. Hennig, R. Bertermann, M. Grüne, F. Würthner, N. V. Ignat'ev, M. Finze,
Chem. Eur. J., 2018, 24, 608. |
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Chlorocyanoborates: Synthesis, Spectroscopic and Structural Characterization, and Properties of Ionic Liquids
L. A. Bischoff, J. A. P. Sprenger, P. T. Hennig, N. V. Ignat'ev, M. Finze,
Z. Anorg. Allg. Chem., 2018, 644, 1285. |
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Synthesis of novel porous coordination polymers from structured and functionalized ionic liquid media
Solubility of molecular and ionic precursors in ionic liquids
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Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids
L. Schmolke, S. Lerch, M. Bühlow, M. Siebels, A. Schmitz, J. Thomas, G. Dehm, C. Held, Th. Strassner, C. Janiak,
Dalton Trans., 2019, 11, 4073.
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Thermodynamic properties of selenoether-functionalized ionic liquids and their use for the synthesis of zinc selenide nanoparticles
K. Klauke, D. H. Zaitsau, M. Bülow, L. He, M. Klopotowski, T.-O. Knedel, J. Barthel, C. Held, S. P. Verevkin, C. Janiak,
Dalton Trans., 2018, 47 (14), 5083-5097.
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Energetic structure-property relationships in thermochemistry of halogenosubstituted benzoic acids
K. V. Zherikova, S. P. Verevkin,
Journal of Thermal Analysis and Calorimetry, 2018, accepted JTAC-S-18-01885.
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Melting temperature and heat of fusion of cytosine revealed from fast scanning calorimetry
A. Abdelaziz, D. H, Zaitsau, T. A. Mukhametzyanov, B. N. Solomonov, P. Cebe, S. P. Verevkin, C. Schick,
Thermochimica Acta , 2017, 657, 47-55.
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Understanding solution based syntheses of inorganic materials in ionic liquids: Peering into the reaction mechanism from birth to age
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Ionothermal synthesis of crystalline microporous aluminophosphates: Systematic study on the conditions affecting the framework type
M. M. Azim, A. Pensado, B. Kirchner, T. Gutmann, P. B. Groszewicz, G. Buntkowsky, A. Stark,
Microporous and Mesoporous Mater., 2018, 266, 204-213.
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Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO2 in Ionic Liquids
P. Voepel, C. Seitz, J. M. Waack, S. Zahn, T. Leichtweiß, A. Zaichenko, D. Mollenhauer, H. Amenitsch, M. Voggenreiter, S. Polarz, B. M. Smarsly,
Cryst. Growth Des. , 2017, 17 (10), 5586-5601.
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Hydrophilic Ionic Liquid Mixtures of Weakly and Strongly Coordinating Anions with and without Water
R. Macchieraldo, L. Esser, R. Elfgen, P. Voepel, S. Zahn, B. M. Smarsly, B. Kirchner,
ACS Omega, 2018, 3, 8567-8582.
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Structure and lifetimes in ionic liquids and their mixtures
S. Gehrke, M. von Domaros, R. Clark, O. Hollóczki, M. Brehm, T. Welton, A. Luzar, B. Kirchner,
Faraday Discuss., 2018, 206, 219-245.
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Halogenated materials from novel reactive halogenating ionic liquids
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Low-Melting Manganese(II)-Based Ionic Liquids: Syntheses, Structures, Properties and Influence of Trace Impurities
T. Peppel, M. Geppert-Rybczynska, C. Neise, U. Kragl, M. Köckerling,
Materials, 2019, 12, 3764. |
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Low Melting Tetracyanidoborate Salts with Alkyl-, Arylammonium, and Pyridinium Cations: Syntheses, Structures, Properties
A. Siegesmund, A. Topp, C. Nitschke, M. Köckerling,
ChemistrySelect, 2017, 2, 11328-11335. |
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New Early Transition Metal Atom Cluster Materials: In and with Ionic Liquids
ILPIN: Ionic Liquid Precursors for Multicomponent Inorganic Nanomaterials
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CuS nanoplates from ionic liquid precursors—Application in organic photovoltaic
cells
Y. Kim, B. Heyne, A. Abouserie, Ch. Pries, Ch. Ippen, Ch. Günter, A. Taubert, A. Wedel,
J. Chem. Phys., 2018, 148, 193818.
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Reducible oxide materials: knowledge-driven design of novel low-temperature synthesis routes
Low-temperature Synthesis of Thermoelectric Materials by Thermal Decomposition of Tailor-made Precursors in Ionic Liquids
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Ionic Liquid-Based Low-Temperature Synthesis of Phase-Pure Tetradymite-Type Materials and Their Thermoelectric Properties
M. Loor, S. Salloum, P. Kawulok, S. Izadi, G. Bendt, J. Guschlbauer, J. Sundermeyer, N. Pérez, K. Nielsch, G. Schierning, S. Schulz,
Inorg. Chem., 2020, accepted
DOI: doi.org/10.1021/acs.inorgchem.9b03060 |
Thermochemical investigations of phase formation processes of elements and compounds of group 15 and 16 in ionic liquid based synthesis - Mechanism of dissolution, structure formation and precipitation
Pseudohalogen Chemistry in Ionic Liquids with Non-innocent Cations and Anions
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Cyanidosilicates – Synthesis and Structure
J. Harloff, D. Michalik, S. Nier, A. Schulz, P. Stoer, A. Villinger,
Angew. Chem. Int. Ed. , 2019, 58, 5452-5456.
Angew. Chem., 2019, 131, 5506-5511.
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Chalcogenide-based Ionic Liquids in the Synthesis of Metal Chalcogenide and Interchalcogenide Materials near Room Temperature
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Ionic Liquid-Based Low-Temperature Synthesis of Phase-Pure Tetradymite-Type Materials and Their Thermoelectric Properties
M. Loor, S. Salloum, P. Kawulok, S. Izadi, G. Bendt, J. Guschlbauer, J. Sundermeyer, N. Pérez, K. Nielsch, G. Schierning, S. Schulz,
Inorg. Chem., 2020, accepted
DOI: doi.org/10.1021/acs.inorgchem.9b03060 |
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Systematic study on anion–cation interactions via doubly ionic H-bonds in 1,3-dimethylimidazolium salts comprising chalcogenolate anions MMIm [ER] (E = S, Se; R = H, tBu, SiMe3)
J. Guschlbauer, T. Vollgraff, J. Sundermeyer,
Dalton Trans, 2019, 48, 10971–10978.
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CURRENT EVENTS
RECENT PUBLICATIONS
CONTACT
Project Assistant
Alina Markova, M.A.
Phone: +49 351 463-31692
Fax: +49 351 463-37287
Email: spp1708(at)chemie.tu-dresden.de
Office:
Bergstraße 66,
Neubau Chemische Institute,
Room 455
Mail to:
TU Dresden
Fakultät Chemie
und Lebensmittelchemie
Professur für Anorganische Chemie II
01062 Dresden
Bulk mail to:
Fakultät Chemie
und Lebensmittelchemie
Professur für Anorganische Chemie II
Helmholtzstraße 10
01069 Dresden
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